What mostly sets my alarm bells about Ron/Hermione is Ron's jealousy tbh. Ron is generally a good and loving person, but he has a terrible inferiority complex, and with a brilliant girl like Hermione, it just wouldn't work. Maybe I'm projecting, but I think he wouldn't feel good about her successes, especially academic. Hermione would end up either being mad at him all the time, or feeling guilty about being intelligent.
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What mostly sets my alarm bells about Ron/Hermione is Ron's jealousy tbh. Ron is generally a good and loving person, but he has a terrible inferiority complex, and with a brilliant girl like Hermione, it just wouldn't work. Maybe I'm projecting, but I think he wouldn't feel good about her successes, especially academic. Hermione would end up either being mad at him all the time, or feeling guilty about being intelligent.